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Blackstone River TMDL Water Quality  
Project Title:
Quantification and Analysis of In-Stream Nutrient and Trace Element Transport in the Massachusetts Segment of the Blackstone River
Start Date:
2006
End Date:
2009
Location:
Blackstone River
Funding Source:
Massachusetts Department of Environmental Protection and USGS Cooperative Water Program
Contact:
Robert Breault
Team:
Robert Breault, Marcus Waldron, Kirk Smith, Gerry Girouard, Kimberly Campo, Andrew Waite

Problem
Excessive nutrient and trace metal levels have been identified as the causes of poor water quality in the Blackstone River and Narragansett Bay (Wright and others, 2001). Reductions are needed in both point- and non-point-source loadings to reduce the amounts of nutrients and trace metals released to the river and estuary. This is part of a comprehensive multi-state (Massachusetts and Rhode Island) effort to achieve contaminant-load reductions to restore water quality in both the Blackstone River and Narragansett Bay.

Nitrogen loading from point- and non-point-sources, including stormwater, treated wastewater, bottom sediment, and combined sewage from numerous POTWs and combined sewer overflows (CSOs) is of particular concern in the Blackstone River Drainage Area. For example, excessive nitrogen levels have been identified as the trigger for algal blooms and dissolved oxygen deficits observed in Narragansett Bay. In-stream losses of nitrogen (nitrogen attenuation) may reduce the impact of (far) upstream sources relative to downstream sources. However, the location and extent of nitrogen attenuation along the river are unknown. Precise measurements of nitrogen attenuation are needed to partition permissible nitrogen loadings among sources and develop strategies for nitrogen removal in the MA section of the river. Available nitrogen models (for example, SPARROW) use nitrogen attenuation rates which may not be applicable to the Blackstone River, because such rates vary dramati Problem cally among rivers and streams. Therefore, field measurements to assess site-specific rates for the Blackstone River are needed.

Scouring of riverbanks and bottom-sediment deposits may be substantial non-point sources of nutrients and trace elements to the river. Flow fluctuations due to precipitation, runoff, and hydropower operations may increase bank scouring and resuspension of bottom sediment. Resuspended material with associated contamination moves into the water column and is transported and redeposited downstream. Currently, there is no quantitative information on the amounts of contaminated sediment moving through the system or the hydrologic factors that determine whether a given impoundment acts as a source, sink, or both for contaminated sediment.

 

Objectives
Measure bi-weekly, monthly, seasonal, and annual loads of nutrients and trace metals contributed to the RI portion of the Blackstone River Basin by the MA portion; Assess the potential for resuspension and transport of previously deposited, nutrient- and metal-enriched bottom sediment; and, determine the potential for nitrogen attenuation by means of mass balance in the Massachusetts portion of the river

 

Approach
Objective 1:

Nutrient and trace-metal loading from the MA segment of the Blackstone River to the RI segment will be measured for one year (May 2007 –May 2008). Loads during low (base) and high (storm and controlled releases) flows will be measured separately during this period. Water-quality samples for chemical analysis will be collected using a newly developed automated sampling device.
Conditions exist that preclude situating the USGS streamflow-monitoring station exactly at the MA-RI State Line. Consequently, parts of the Massachusetts portion of the mainstem will not be gaged or sampled. Existing nitrogen models will be evaluated for nutrient loading from these areas.

Objective 2:

The resuspension and transport of previously deposited, nutrient- and metal-enriched bottom sediment from two MA impoundments, Rice City Pond and Rockdale Pond will be assessed by continuously measuring stage, turbidity, or Chlorophyll.
Instantaneous measurements of streamflow, turbidity, Chlorophyll, and element and suspended-sediment concentrations will also be made. Equations that relate element and suspended-sediment concentrations to turbidity will be developed and used to estimate continuous loads from continuous turbidity and stage measurements. Next, a mass-balance approach will be used to determine whether or not contaminated bottom sediment are resuspended and transported at a range of flow conditions.

Objective 3:

The mass of nitrogen discharged to the Blackstone River by the Upper Blackstone Water Pollution Abatement District (UBWPAD) that is attenuated within the Massachusetts portion of the river will be estimated by means of a mass balance approach. Nitrogen loads will be measured during base flow and storms separately at streamflow and water-quality monitoring stations located throughout the MA portion of the Blackstone River. Streamflow will be measured continuously for eight months (May—December, 2007). Water samples for chemical analysis will be collected over a 14-day period during each month using an automated sampling device. Other nitrogen sources to the Blackstone River include POTW’s, tributaries, and non-point sources. Nitrogen concentration data for POTW discharges will be obtained from direct measurement. For the wastewater treatment plants at Millbury (UBWPAD), Grafton, Northbridge, and Uxbridge; daily samples of wastewater effluent collected by the treatment plant operators will be composited into a bi-monthly (14 day) samples that will be analyzed for nutrients and suspended-sediment concentration. Discharge will be obtained from treatment plant operators. Other loads must be estimated using existing water-quality models. Calculations of in-stream nitrogen mass flux entering and exiting each reach will indicate when and where nitrogen removal processes are significant.

 

References
Linsley, R.K., Kohler, M.A. and Paulus, J.L.H. Hydrology for Engineers (3rd ed.), McGraw-Hill, New. York, 1982 508pp.

Wilde, F.D., Radtke, D.B., Gibs, Jacob, and Iwatsubo, R.T., 1999, Collection of Water Samples, in National field manual for the collection of water-quality data: U.S. Geological Survey Techniques of Water-Resources Investigations, book 9, chap. A4.

Wright, R.M., Nolan, P.M., Pincumbe, D., Hartman, E., and Viator, O.J., 2001, Blackstone River Initiative: water quality analysis of the Blackstone River under wet and dry weather conditions: University of Rhode Island, Kingston, RI., variously paged.

 


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